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Since rate constants for thiol-disulfide exchange is optimal when the thiol pKa value is equal to the solution pH value, T[SH] 2 is more reactive than GSH under physiological conditions

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Thus, the relatively long elimination half-life of adducts, an indicator of the oxidative metabolism of APAP, suggests that this biomarker could be useful in the clinical setting and has specificity for APAP-mediated liver injury

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10.1152/ajpheart.00347.2005 63 NrgaardC